1. Hoʻolauna
ʻO EVA ka pōkole no ka ethylene vinyl acetate copolymer, he polymer polyolefin. Ma muli o kona mahana hoʻoheheʻe haʻahaʻa, ka maikaʻi o ka wai, ka polarity a me nā mea ʻaʻole halogen, a hiki ke hoʻohālikelike ʻia me nā ʻano polymers a me nā pauka mineral, he nui nā waiwai mechanical a me ke kino, nā waiwai uila a me ke kaulike hana hana, a ʻaʻole kiʻekiʻe ke kumukūʻai, ua lawa ka lako mākeke, no laila ʻo nā mea insulation uwea ʻelua, hiki ke hoʻohana ʻia ma ke ʻano he mea hoʻopihapiha, mea uhi; hiki ke hana ʻia i mea thermoplastic, a hiki ke hana ʻia i mea thermosetting cross-linking.
ʻO ka laulā o nā hoʻohana EVA, me nā mea pale ahi, hiki ke hana ʻia i mea pale wahie halogen-free haʻahaʻa a i ʻole halogen; koho i ka ʻike VA kiʻekiʻe o EVA ma ke ʻano he mea kumu hiki ke hana ʻia i mea pale ʻaila; koho i ka helu heheʻe o EVA waena, e hoʻohui i 2 a 3 mau manawa o ka hoʻopiha ʻana o nā mea pale ahi EVA i ka hana extrusion a me ke kumukūʻai o kahi mea pale oxygen (hoʻopiha) ʻoi aku ka kaulike.
Ma kēia pepa, mai nā waiwai hoʻonohonoho o EVA, ka hoʻolauna ʻana i kāna noi ma ka ʻoihana kaula a me nā manaʻolana hoʻomohala.
2. Nā waiwai kūkulu
I ka wā e hana ai i ka synthesis, ʻo ka hoʻololi ʻana i ka lakio o ke kekelē polymerisation n / m hiki ke hana i ka ʻike VA mai 5 a 90% o EVA; ʻo ka hoʻonui ʻana i ke kekelē polymerisation holoʻokoʻa hiki ke hana i ke kaumaha molekala mai nā ʻumi tausani a i nā haneli haneli o EVA; ʻO ka ʻike VA ma lalo o 40%, ma muli o ke alo o ka crystallization hapa, elasticity haʻahaʻa, i ʻike pinepine ʻia ʻo EVA plastic; i ka wā e ʻoi aku ai ka ʻike VA ma mua o 40%, ʻo kahi elastomer e like me ka rubber me ka ʻole o ka crystallization, i ʻike pinepine ʻia ʻo EVM rubber.
1. 2 mau waiwai
He ʻano saturated linear ke kaulahao molekala o EVA, no laila he maikaʻi kona kūpaʻa ʻana i ka wela, ke aniau a me ke kūpaʻa ʻana i ka ozone.
ʻAʻohe o nā kaulahao nui o ka molekala EVA i nā pilina pālua, ke apo benzene, ka acyl, nā hui amine a me nā hui ʻē aʻe e maʻalahi ke puhi ʻia i ka wā e puhi ai, ʻaʻole hoʻi i loko o nā kaulahao ʻaoʻao ka maʻalahi ke puhi ʻia i ka wā e puhi ai i ka methyl, phenyl, cyano a me nā hui ʻē aʻe. Eia kekahi, ʻaʻohe o ka molekala ponoʻī i nā mea halogen, no laila kūpono loa ia no ke kumu wahie resistive halogen-free haʻahaʻa.
ʻO ka nui o ka hui vinyl acetate (VA) i loko o ke kaulahao ʻaoʻao EVA a me kona polarity waena, ʻo ia hoʻi ke kāohi nei i ke ʻano o ka iwi kuamoʻo vinyl e crystallise a hui maikaʻi me nā mea hoʻopihapiha mineral, kahi e hana ai i nā kūlana no nā wahie pale hana kiʻekiʻe. He ʻoiaʻiʻo loa kēia no nā mea pale uahi haʻahaʻa a me nā mea pale halogen-free, ʻoiai he mau mea pale lapalapa me ka ʻoi aku ma mua o 50% o ka nui o ka leo [e.g. Al(OH)3, Mg(OH)2, etc.] pono e hoʻohui ʻia e hoʻokō i nā koi o nā kūlana kaula no ka pale lapalapa. Hoʻohana ʻia ʻo EVA me ka nui o ka VA waena a kiʻekiʻe ma ke ʻano he kumu e hana ai i nā wahie pale lapalapa haʻahaʻa a me nā mea pale halogen-free me nā waiwai maikaʻi loa.
ʻOiai he polar ka hui vinyl acetate kaulahao ʻaoʻao EVA (VA), ʻo ke kiʻekiʻe o ka nui o ka VA, ʻoi aku ka polar o ka polymer a ʻoi aku ka maikaʻi o ke kūʻē ʻana i ka ʻaila. ʻO ke kūʻē ʻaila e koi ʻia e ka ʻoihana kaula e pili ana i ka hiki ke kū i nā aila mineral non-polar a nāwaliwali paha. Wahi a ke kumumanaʻo o ka hoʻohālikelike like, hoʻohana ʻia ka EVA me ka nui o ka VA ma ke ʻano he mea kumu e hana ai i kahi pale wahie haʻahaʻa a me ka halogen-free me ke kūʻē ʻana i ka ʻaila maikaʻi.
ʻOi aku ka hana o nā molekala EVA i loko o ka alpha-olefin H atom, i ka hopena peroxide a i ʻole ka ikehu kiʻekiʻe o ka electron-radiation, maʻalahi ka hana H cross-linking, a lilo i plastic cross-linked a i ʻole ka laholio, hiki ke hana i nā koi hana koi o nā mea uea a me nā kaula kūikawā.
ʻO ka hoʻohui ʻana o ka hui vinyl acetate e hoʻohaʻahaʻa nui i ka mahana heheʻe o ka EVA, a ʻo ka helu o nā kaulahao ʻaoʻao pōkole VA e hiki ai ke hoʻonui i ke kahe o ka EVA. No laila, ʻoi aku ka maikaʻi o kāna hana extrusion ma mua o ke ʻano molekala o ka polyethylene like, e lilo ana i mea kumu makemake ʻia no nā mea pale semi-conductive a me nā pale wahie halogen a me halogen-free.
2 Nā pono o ka huahana
2. 1 Hana kumukūʻai kiʻekiʻe loa
He maikaʻi loa nā waiwai kino a me nā waiwai mechanical o EVA, ke kūpaʻa wela, ke kūpaʻa ʻana i ka wā, ke kūpaʻa ʻana i ka ozone, nā waiwai uila. E koho i ka papa kūpono, hiki ke hana i ke kūpaʻa wela, hana pale ahi, akā ʻo ka ʻaila a me ka mea uwea kūikawā e kū'ē i ka solvent.
Hoʻohana nui ʻia ka mea EVA Thermoplastic me ka nui o ka VA o 15% a 46%, me ka helu hoʻoheheʻe o 0.5 a 4 mau māka. He nui nā mea hana o EVA, he nui nā lama, kahi ākea o nā koho, nā kumukūʻai kūpono, ka lako lawa, pono nā mea hoʻohana e wehe i ka ʻāpana EVA o ka pūnaewele, ka lama, ka hana, ke kumukūʻai, ka wahi hoʻouna i ka nānā ʻana, hiki iā ʻoe ke koho, maʻalahi loa.
He polymer polyolefin ʻo EVA, mai ka palupalu a me ka hoʻohana ʻana i nā hoʻohālikelike hana, a like ka mea polyethylene (PE) a me ka mea kaula polyvinyl chloride (PVC) palupalu. Akā ma ka noiʻi hou ʻana, e ʻike ʻoe iā EVA a me nā ʻano mea ʻelua i luna aʻe me ka ʻoi aku ka maikaʻi ʻole.
2. 2 hana hoʻoponopono maikaʻi loa
ʻO ka EVA i ka hoʻohana ʻana i ke kaula uila mai ka mea pale uwea uila waena a me ke kiʻekiʻe i loko a ma waho o ka hoʻomaka, a ma hope e hoʻonui ʻia i ka pale wahie halogen-free. Mai ka manaʻo hana, ua manaʻo ʻia kēia mau ʻano mea ʻelua he "mea i hoʻopiha nui ʻia": no ka mea pale, pono e hoʻohui i ka nui o ke kalapona ʻeleʻele conductive a hoʻonui i kona viscosity, hāʻule nui ka wai; no ka wahie halogen-free flame retardant, pono e hoʻohui i ka nui o nā halogen-free flame retardants, a no ka mea halogen-free viscosity hoʻi, ua hāʻule nui ka wai. ʻO ka hopena, ʻo ia ka loaʻa ʻana o kahi polymer e hiki ke hoʻokipa i nā nui o ka hoʻopiha, akā he haʻahaʻa hoʻi ka viscosity heheʻe a me ka wai maikaʻi. No kēia kumu, ʻo EVA ke koho makemake nui ʻia.
ʻO ka mānoanoa heheʻe EVA me ka mahana hana extrusion a me ka wikiwiki shear e hoʻonui i ka emi wikiwiki, pono ka mea hoʻohana e hoʻoponopono i ka mahana extruder a me ka wikiwiki o ka wili, hiki iā ʻoe ke hana i ka hana maikaʻi loa o nā huahana uea a me ke kaula. Hōʻike ka nui o nā noi kūloko a me nā haole, no ka mea ua piha loa ka uahi haʻahaʻa halogen-free, no ka mea ua nui loa ka viscosity, ua liʻiliʻi loa ka helu hoʻoheheʻe, no laila ʻo ka hoʻohana wale ʻana i ka wili ratio compression haʻahaʻa (ka lakio compression o ka liʻiliʻi ma mua o 1.3) extrusion, i mea e hōʻoia ai i ka maikaʻi o ka extrusion. Hiki ke hoʻokuʻu ʻia nā mea EVM i hoʻokumu ʻia i ka rubber me nā mea vulcanising ma nā extruders rubber a me nā extruders kumu maʻamau. Hiki ke hoʻokō ʻia ke kaʻina hana vulcanisation (cross-linking) ma hope ma o ka thermochemical (peroxide) cross-linking a i ʻole ma o ka electron accelerator irradiation cross-linking.
2. 3 Maʻalahi e hoʻololi a hoʻololi
Aia nā uea a me nā kaula ma nā wahi a pau, mai ka lani a i ka honua, mai nā mauna a i ke kai. He ʻokoʻa a he ʻano ʻē hoʻi nā koi o ka poʻe hoʻohana i ka uea a me ke kaula, ʻoiai ke ʻano like o ka uea a me ke kaula, ʻike nui ʻia kona ʻokoʻa hana i nā mea uhi insulation a me ka sheath.
A hiki i kēia manawa, ma ka home a ma waho hoʻi, ʻo ka PVC palupalu ke kumu nui o nā mea polymer i hoʻohana ʻia i ka ʻoihana kaula. Eia nō naʻe, me ka hoʻonui ʻana o ka ʻike i ka palekana o ke kaiapuni a me ka hoʻomohala hoʻomau.
Ua kaupalena nui ʻia nā mea PVC, ke hana nei nā kānaka ʻepekema i nā mea āpau e hiki ai ke loaʻa nā mea ʻē aʻe i ka PVC, ʻo ka mea hoʻohiki nui loa ʻo EVA.
Hiki ke hoʻohuihui ʻia ʻo EVA me nā ʻano polymers like ʻole, akā me nā ʻano pauka mineral like ʻole a me nā mea kōkua hana e kūpono ana, hiki ke hana ʻia nā huahana i hoʻohuihui ʻia i loko o ka plastic thermoplastic no nā kaula plastik, akā i loko o ka rubber cross-linked no nā kaula rubber. Hiki ke hoʻokumu ʻia nā mea hoʻolālā formulation ma nā koi o ka mea hoʻohana (a i ʻole maʻamau), ʻo EVA ma ke ʻano he mea kumu, e hana i ka hana o ka mea e hoʻokō i nā koi.
3 laulā noi EVA
3. 1 Hoʻohana ʻia ma ke ʻano he mea pale semi-conductive no nā kaula mana kiʻekiʻe
E like me kā kākou e ʻike nei, ʻo ka mea nui o ka mea pale he kalapona ʻeleʻele alakaʻi, i loko o ka mea kumu plastik a i ʻole ka laholio e hoʻohui i ka nui o ke kalapona ʻeleʻele e hōʻino nui i ka wai o ka mea pale a me ka laumania o ka pae extrusion. I mea e pale ai i nā hoʻokuʻu hapa i nā kaula voltage kiʻekiʻe, pono nā pale o loko a me waho e lahilahi, ʻālohilohi, ʻālohilohi a like. Ke hoʻohālikelike ʻia me nā polymers ʻē aʻe, hiki i ka EVA ke hana maʻalahi i kēia. ʻO ke kumu o kēia, ʻo ia ka maikaʻi loa o ke kaʻina hana extrusion a EVA, kahe maikaʻi, a ʻaʻole hiki ke hoʻoheheʻe ʻia ka hanana haki. Ua māhele ʻia ka mea pale i ʻelua mau ʻāpana: i wahī ʻia i loko o ke alakaʻi ma waho i kapa ʻia ʻo ka pale o loko - me ka mea pale o loko; i wahī ʻia i loko o ka insulation ma waho i kapa ʻia ʻo ka pale o waho - me ka mea pale o waho; ʻo ka mea pale o loko he thermoplastic ka hapa nui o ka mea pale o loko a ua hoʻokumu pinepine ʻia ma EVA me ka ʻike VA o 18% a 28%; ʻo ka mea pale o waho he cross-linked a hiki ke peelable a ua hoʻokumu pinepine ʻia ma EVA me ka ʻike VA o 40% a 46%.
3. 2 Nā wahie pale ahi Thermoplastic a me nā mea i hoʻopili ʻia
Hoʻohana nui ʻia ka polyolefin pale ahi thermoplastic i ka ʻoihana kaula, ʻo ia hoʻi no nā koi halogen a i ʻole halogen-free o nā kaula moana, nā kaula mana a me nā laina kūkulu kiʻekiʻe. ʻO ko lākou mahana hana lōʻihi mai 70 a 90 °C.
No nā kaula mana uila waena a me ke kiʻekiʻe o 10 kV a ʻoi aku, nona nā koi hana uila kiʻekiʻe loa, ʻo nā waiwai pale ahi e halihali nui ʻia e ka ʻūpā waho. I kekahi mau hale a i ʻole nā papahana e koi ana i ke kaiapuni, pono nā kaula e loaʻa i ka uahi haʻahaʻa, ʻaʻohe halogen, haʻahaʻa ka ʻawahia a i ʻole haʻahaʻa ka uahi a me nā waiwai halogen haʻahaʻa, no laila he hopena kūpono nā polyolefins pale ahi thermoplastic.
No kekahi mau kumu kūikawā, ʻaʻole nui ke anawaena o waho, kū'ē i ka mahana ma 105 ~ 150 ℃ ma waena o ke kaula kūikawā, ʻoi aku ka nui o ka mea polyolefin flame retardant cross-linked, hiki ke koho ʻia kona cross-linking e ka mea hana kaula e like me kā lākou mau kūlana hana ponoʻī, ʻo ia hoʻi ke kahe kiʻekiʻe kuʻuna a i ʻole ka ʻauʻau paʻakai wela kiʻekiʻe, akā loaʻa pū kekahi ala cross-linked electron accelerator irradiation temperature room irradiation. Ua māhele ʻia kona mahana hana lōʻihi i 105 ℃, 125 ℃, 150 ℃ ʻekolu mau faila, hiki ke hana ʻia ka hale hana hana e like me nā koi like ʻole o nā mea hoʻohana a i ʻole nā kūlana, halogen-free a i ʻole halogen-containing wahie barrier.
Ua ʻike maopopo ʻia he mau polymer polar non-polar a nāwaliwali paha nā polyolefins. ʻOiai ua like lākou me ka ʻaila mineral ma ke polarity, ua manaʻo nui ʻia nā polyolefins he emi ke kūpaʻa i ka ʻaila e like me ke kumumanaʻo o ka hoʻohālikelike like. Eia nō naʻe, ua ʻōlelo pū kekahi mau kūlana uwea ma ka home a ma waho e pono i nā pale cross-linked ke kūpaʻa maikaʻi i nā ʻaila, nā mea hoʻoheheʻe a hiki i nā slurries ʻaila, nā waikawa a me nā alkalis. He pilikia kēia no nā mea noiʻi mea, i kēia manawa, inā ma Kina a ma waho paha, ua hoʻomohala ʻia kēia mau mea koi, a ʻo kāna mea kumu ʻo EVA.
3. 3 Mea pale oxygen
He nui nā hakahaka ma waena o nā ʻiwi o nā kaula multi-core i hoʻopaʻa ʻia e pono e hoʻopiha ʻia e hōʻoia i kahi ʻano poepoe o ke kaula, inā hana ʻia ka hoʻopiha ʻana i loko o ka ʻūpā waho me ka pale wahie halogen-free. Hana kēia papa hoʻopihapiha ma ke ʻano he pale lapalapa (oxygen) i ka wā e ʻā ai ke kaula a no laila ua kapa ʻia ʻo ia he "pale oxygen" i ka ʻoihana.
ʻO nā koi kumu no kahi mea pale oxygen: nā waiwai extrusion maikaʻi, ka pale ahi halogen-free maikaʻi (ʻoi aku ka nui o ka oxygen index ma mua o 40) a me ke kumu kūʻai haʻahaʻa.
Ua hoʻohana nui ʻia kēia pale oxygen i ka ʻoihana kaula no nā makahiki he ʻumi a ʻoi a ua alakaʻi i nā hoʻomaikaʻi koʻikoʻi i ka pale ʻana i ka lapalapa o nā kaula. Hiki ke hoʻohana ʻia ka pale oxygen no nā kaula pale ahi halogen-free a me nā kaula pale ahi halogen-free (e laʻa me PVC). Ua hōʻike ʻia ka nui o ka hana ʻana he ʻoi aku ka nui o nā kaula me kahi pale oxygen e hala i nā hoʻāʻo puhi kū hoʻokahi a me ka puhi pūʻolo.
Mai ka manaʻo o ka hoʻohuihui ʻana o nā mea, ʻo kēia mea pale oxygen he "mea hoʻopihapiha ultra-kiʻekiʻe", no ka mea, no ka hoʻokō ʻana i ke kumukūʻai haʻahaʻa, pono e hoʻohana i kahi mea hoʻopihapiha kiʻekiʻe, no ka hoʻokō ʻana i kahi helu oxygen kiʻekiʻe pono e hoʻohui i kahi hapa kiʻekiʻe (2 a 3 mau manawa) o Mg (OH) 2 a i ʻole Al (OH) 3, a no ka hoʻopuka maikaʻi ʻana a pono e koho iā EVA ma ke ʻano he mea kumu.
3. 4 Mea uhi PE i hoʻololi ʻia
ʻO nā mea uhi polyethylene he mea maʻalahi i ʻelua mau pilikia: ʻo ka mea mua, he maʻalahi lākou i ka haki ʻana o ka heheʻe (ʻo ia hoʻi ka ʻili manō) i ka wā o ka extrusion; ʻo ka lua, he maʻalahi lākou i ka haki ʻana o ke kaiapuni. ʻO ka hopena maʻalahi loa ka hoʻohui ʻana i kahi hapa o EVA i loko o ka hoʻohuihui. hoʻohana ʻia ma ke ʻano he EVA i hoʻololi ʻia me ka hoʻohana ʻana i ka ʻike VA haʻahaʻa o ka papa, kūpono kona helu hoʻoheheʻe ma waena o 1 a 2.
4. Nā manaʻolana hoʻomohala
(1) Ua hoʻohana nui ʻia ka EVA i ka ʻoihana kaula, a ua ulu mālie a paʻa ka nui o kēlā me kēia makahiki. ʻOi loa aku i nā makahiki he ʻumi i hala iho nei, ma muli o ke koʻikoʻi o ka palekana o ke kaiapuni, ua wikiwiki ka ulu ʻana o ke kūpaʻa wahie EVA, a ua pani hapa i ke ʻano o nā mea kaula PVC. ʻO kāna hana kumukūʻai maikaʻi loa a me ka hana maikaʻi loa o ke kaʻina hana extrusion he mea paʻakikī ke pani i nā mea ʻē aʻe.
(2) ʻO ka hoʻohana makahiki ʻana o ka ʻoihana uwea o ka resin EVA kokoke i 100,000 tons, ʻo ke koho ʻana o nā ʻano resin EVA, e hoʻohana ʻia ka nui o ka VA mai ka haʻahaʻa a i ke kiʻekiʻe, me ka hui pū ʻana me ka nui o ka granulation o nā mea uwea ʻaʻole nui ka nui o ka ʻoihana, hoʻolaha ʻia i kēlā me kēia ʻoihana i kēlā me kēia makahiki i nā tausani tons o ka resin EVA i luna a i lalo, a no laila ʻaʻole e nānā nui ʻia ka ʻoihana EVA. No ka laʻana, ʻo ka nui o nā mea kumu halogen-free flame retardant, ʻo ke koho nui o VA / MI = 28 /2 ~ 3 o ka resin EVA (e like me ka US DuPont's EVA 265 #). A ʻo kēia papa kikoʻī o EVA a hiki i kēia manawa ʻaʻohe mea hana kūloko e hana a hoʻolako. ʻAʻole e haʻi i ka ʻike VA ma mua o 28, a ʻo ka helu hoʻoheheʻe ma lalo o 3 o ka hana a me ka hoʻolako ʻana o nā resin EVA ʻē aʻe.
(3) ʻO nā ʻoihana haole e hana ana i ka EVA ma muli o ka ʻole o nā mea hoʻokūkū kūloko, a ua lōʻihi ke kiʻekiʻe o ke kumukūʻai, e kāohi nui ana i ka hoihoi o ka hana ʻana o nā hale hana uwea kūloko. ʻOi aku ma mua o 50% o ka nui o ka VA o ka EVM ʻano laholio, he ʻoihana haole i hoʻomalu ʻia, a ua like ke kumukūʻai me ka nui o ka VA o ka brand 2 a 3 mau manawa. ʻO kēlā mau kumukūʻai kiʻekiʻe, ma ka huli ʻana, e hoʻopilikia pū i ka nui o kēia ʻano EVM ʻano laholio, no laila ke kāhea nei ka ʻoihana uwea i nā mea hana EVA kūloko, e hoʻomaikaʻi i ka wikiwiki o ka hana ʻana o EVA kūloko. ʻO ka nui o ka hana ʻana o ka ʻoihana ua nui ka hoʻohana ʻana i ka resin EVA.
(4) Ma muli o ka nalu o ka palekana o ke kaiapuni i ke au o ka globalization, ua manaʻo ʻia ʻo EVA e ka ʻoihana kaula ʻo ia ke kumu maikaʻi loa no ke kūpaʻa ʻana i ka wahie aloha kaiapuni. Ke ulu nei ka hoʻohana ʻana o EVA ma ka wikiwiki o 15% i kēlā me kēia makahiki a he mea hoʻohiki nui ka nānā ʻana. ʻO ka nui a me ka wikiwiki o ka ulu ʻana o nā mea pale a me ka hana ʻana o ke kaula mana uila waena a kiʻekiʻe a me ka wikiwiki o ka ulu ʻana, ma kahi o 8% a 10% ma waena; ke ulu wikiwiki nei nā kū'ē polyolefin, i nā makahiki i hala iho nei ua noho mau ma 15% a 20% ma waena, a i nā makahiki 5 a 10 e hiki mai ana, hiki ke mālama i kēia wikiwiki o ka ulu ʻana.
Ka manawa hoʻouna: Iulai-31-2022